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For the reaction 2 KClO3(s) For the reaction 2 KClO<sub>3</sub>(s)    2 KCl (s)  + 3 O₂(g) , K c = 2.0 at 750 C. What is the equilibrium concentration of O₂? A)  2.0 M B)  (2.0) <sup>1/3</sup> M C)  (2.0) <sup> - 1/3</sup> M D)  8.0 M E)  (8.0) <sup> - 1</sup> M 2 KCl (s) + 3 O₂(g) , K c = 2.0 at 750 C. What is the equilibrium concentration of O₂?


A) 2.0 M
B) (2.0) 1/3 M
C) (2.0) - 1/3 M
D) 8.0 M
E) (8.0) - 1 M

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Inert helium gas was injected into a reaction vessel of fixed volume containing an equilibrium mixture of 2 SO₂ (g) + O₂(g) Inert helium gas was injected into a reaction vessel of fixed volume containing an equilibrium mixture of 2 SO₂ (g)  + O₂(g)    2 SO<sub>3</sub>(g) . The pressure was increased from 1.0 atm to 2.0 atm by the adding helium. Which of the following statements describes the new equilibrium system? A)  [SO<sub>3</sub>] increases B)  [SO<sub>2</sub>] increases C)  [SO<sub>3</sub>] decreases D)  [O<sub>2</sub>] increases E)  [SO<sub>3</sub>], [SO<sub>2</sub>], and [O<sub>2</sub>] remain unchanged 2 SO3(g) . The pressure was increased from 1.0 atm to 2.0 atm by the adding helium. Which of the following statements describes the new equilibrium system?


A) [SO3] increases
B) [SO2] increases
C) [SO3] decreases
D) [O2] increases
E) [SO3], [SO2], and [O2] remain unchanged

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At 700 C, the equilibrium constant ( K c ) for the reaction N₂(g) + 3 H₂ (g) At 700 C, the equilibrium constant ( K c )  for the reaction N₂(g)  + 3 H₂ (g)    2 NH₃(g)  is 2.37 10 - 3 . If 0.683 mol of N₂, 8.80 mol of H₂ and 0.744 mole of NH₃are mixed in a 1.00 L container at 700 C: A)  the value of Q is unknown. B)  the value of Q is greater than K <sub>c</sub>. C)  the value of Q is equal to K <sub>c</sub>. D)  the reaction is at equilibrium. E)  the value of Q is less than K <sub>c</sub>. 2 NH₃(g) is 2.37 10 - 3 . If 0.683 mol of N₂, 8.80 mol of H₂ and 0.744 mole of NH₃are mixed in a 1.00 L container at 700 C:


A) the value of Q is unknown.
B) the value of Q is greater than K c.
C) the value of Q is equal to K c.
D) the reaction is at equilibrium.
E) the value of Q is less than K c.

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Consider solving for the molar solubility of a 3:2 electrolyte such as Mg3(PO4) 2. What solubility product expression listed below would be suitable for solving for "x" which could then be related to the solubility of Mg3(PO4) 2?


A) K sp = x5
B) K sp = 4x3
C) K sp = 6x5
D) K sp = 5x5
E) K sp = 108x5

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Mg(OH) 2 ( K sp = 8.9×10 - 12) is precipitated by the addition of strong base to a 0.10 M solution of MgCl2. At what [OH - ] will Mg(OH) 2 begin to precipitate?


A) 1.0 M
B) 0.10 M
C) 9.4×10 - 6 M
D) 2.1×10 - 4 M
E) 8.9×10 - 12 M

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Given: 2 Cl₂ (g) + 2 H₂ O (g) Given: 2 Cl₂ (g)  + 2 H₂ O (g)    4 HCl (g)  + O₂(g)  K c (480 C)  = 0.0752 What would be the equilibrium constant, K c , for the equation that follows? Cl₂ (g)  + H₂ O (g)    2 HCl (g)  + 1 / 2 O₂(g)  K c (480 C)  = ?? A)  5.66×10<sup> - 3</sup> B)  0.0376 C)  0.0752 D)  0.150 E)  0.274 4 HCl (g) + O₂(g) K c (480 C) = 0.0752 What would be the equilibrium constant, K c , for the equation that follows? Cl₂ (g) + H₂ O (g) Given: 2 Cl₂ (g)  + 2 H₂ O (g)    4 HCl (g)  + O₂(g)  K c (480 C)  = 0.0752 What would be the equilibrium constant, K c , for the equation that follows? Cl₂ (g)  + H₂ O (g)    2 HCl (g)  + 1 / 2 O₂(g)  K c (480 C)  = ?? A)  5.66×10<sup> - 3</sup> B)  0.0376 C)  0.0752 D)  0.150 E)  0.274 2 HCl (g) + 1 / 2 O₂(g) K c (480 C) = ??


A) 5.66×10 - 3
B) 0.0376
C) 0.0752
D) 0.150
E) 0.274

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At a certain temperature, for the reaction NH ₄Cl (s) At a certain temperature, for the reaction NH ₄Cl (s)    NH₃(g)  + HCl (g) , K p = 9.0. What is the equilibrium partial pressure of NH₃? A)  9.0 atm B)  0.11 atm C)  3.0 atm D)  0.33 atm E)  0.91 atm NH₃(g) + HCl (g) , K p = 9.0. What is the equilibrium partial pressure of NH₃?


A) 9.0 atm
B) 0.11 atm
C) 3.0 atm
D) 0.33 atm
E) 0.91 atm

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Consider solving for the molar solubility of a 1:3 electrolyte such as Al(OH) 3. After constructing an ICE table and writing a solubility constant expression for this process, what solubility product expression listed below would be suitable for solving for "x" which could then be directly related to the solubility of Al(OH) 3 in water?


A) K sp = 3x3
B) K sp = 27x3
C) K sp = x4
D) K sp = 3x4
E) K sp = 27x4

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For the reaction 2 SO₂ (g) + Cl₂ (g) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)   2 SO₂ Cl₂ (g) , the expression for K c is


A) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)
B) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)
C) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)
D) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)
E) For the reaction 2 SO₂ (g)  + Cl₂ (g)    2 SO₂ Cl₂ (g) , the expression for K c is A)    B)    C)    D)    E)

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A reaction vessel is charged with 1.720 atm of N₂O4 and 1.220 atm of NO₂ at 25 C. The equilibrium reaction is given in the equation below. N₂O4 (g) A reaction vessel is charged with 1.720 atm of N₂O<sub>4</sub> and 1.220 atm of NO₂ at 25 C. The equilibrium reaction is given in the equation below. N₂O<sub>4</sub> (g)    2 NO₂ (g)  After equilibrium is reached, the partial pressure of NO₂ is 0.555 atm. What is the value for the equilibrium constant, K c , of this reaction at 25 C? A)  K <sub>c</sub> = 0.129 B)  K <sub>c</sub> = 0.150 C)  K <sub>c</sub> = 0.222 D)  K <sub>c</sub> = 0.270 E)  K <sub>c</sub> = 6.67 2 NO₂ (g) After equilibrium is reached, the partial pressure of NO₂ is 0.555 atm. What is the value for the equilibrium constant, K c , of this reaction at 25 C?


A) K c = 0.129
B) K c = 0.150
C) K c = 0.222
D) K c = 0.270
E) K c = 6.67

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At 1073 K, the pressure of CO₂ is 0.236 atm when produced by the reaction: CaCO3(s) At 1073 K, the pressure of CO₂ is 0.236 atm when produced by the reaction: CaCO<sub>3</sub>(s)    CaO (s)  + CO₂ (g)  The value of K c for this reaction at 1073 K is (R = 0.0821 L atm/(mol K) ) : A)  0.236 B)  3.59×10<sup> - 3</sup> C)  2.65×10<sup> - 5</sup> D)  2.68×10<sup> - 3</sup> E)  3.55×10<sup> - 5</sup> CaO (s) + CO₂ (g) The value of K c for this reaction at 1073 K is (R = 0.0821 L atm/(mol K) ) :


A) 0.236
B) 3.59×10 - 3
C) 2.65×10 - 5
D) 2.68×10 - 3
E) 3.55×10 - 5

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Consider the following reaction at 1200 K: CH4 (g) + H₂ O (g) Consider the following reaction at 1200 K: CH<sub>4</sub> (g)  + H₂ O (g)    CO (g)  + 3 H₂ (g)  K c = 0.26 What is the pressure equilibrium constant, K p ? A)  K <sub>p</sub> = 0.26; K <sub>p</sub> and K <sub>c</sub> are always equivalent. B)  K <sub>p</sub> = 2.7×10<sup> - 5</sup> C)  K <sub>p</sub> = 1.5×10<sup> - 3</sup> D)  K <sub>p</sub> = 6.6×10<sup>2</sup> E)  K <sub>p</sub> = 2.5×10<sup>3</sup> CO (g) + 3 H₂ (g) K c = 0.26 What is the pressure equilibrium constant, K p ?


A) K p = 0.26; K p and K c are always equivalent.
B) K p = 2.7×10 - 5
C) K p = 1.5×10 - 3
D) K p = 6.6×102
E) K p = 2.5×103

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What is the solubility of PbSO4 ( K sp = 2.0×10 - 8) in a solution that contains 100.0 g of Na2SO4 in 1.00 L?


A) 1.7×10 - 4 M
B) 2.0×10 - 10 M
C) 2.4×10 - 8 M
D) 2.8×10 - 8 M
E) 2.0×10 - 8 M

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For the high temperature equilibrium system, 2 H₂ O (g) For the high temperature equilibrium system, 2 H₂ O (g)    2 H₂ (g)  + O₂(g) , what will be the effect on the equilibrium concentration of O₂(g)  upon: (1)  adding H₂ O (g)  and (2)  decreasing the pressure of the system? A)  (1)  and (2)  increase the concentration of O<sub>2</sub> B)  (1)  increases while (2)  decreases the concentration of O<sub>2</sub> C)  (1)  decreases while (2)  increases the concentration of O<sub>2</sub> D)  (1)  and (2)  decrease the concentration of O<sub>2</sub> E)  none of these 2 H₂ (g) + O₂(g) , what will be the effect on the equilibrium concentration of O₂(g) upon: (1) adding H₂ O (g) and (2) decreasing the pressure of the system?


A) (1) and (2) increase the concentration of O2
B) (1) increases while (2) decreases the concentration of O2
C) (1) decreases while (2) increases the concentration of O2
D) (1) and (2) decrease the concentration of O2
E) none of these

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Exhibit 14-6 Consider the reaction at equilibrium below and its corresponding equilibrium constant to answer the following question(s) . 2 NO₂ (g) Exhibit 14-6 Consider the reaction at equilibrium below and its corresponding equilibrium constant to answer the following question(s) . 2 NO₂ (g)    2 NO (g)  + O₂(g)  K p = 4.48*10<sup>- 13</sup> A pressure of 0.45 atm of NO₂ is introduced into a container and allowed to come to equilibrium. Complete the ICE equilibrium table shown below to get started. Partial pressure S<sub>2</sub>NO₂ 2 NO O₂Initial 0.45 M Change At equilibrium -Refer to Exhibit 14-6. Upon constructing an ICE table, what expression would be obtained that represents the equilibrium partial pressure of NO₂ as it reaches equilibrium? A)  equilibrium P<sub>NO2</sub> = 0.45 atm - x B)  equilibrium P<sub>NO2</sub> = 0.45 atm + x C)  equilibrium P<sub>NO2</sub> = 0.45 atm - 2x D)  equilibrium P<sub>NO2</sub> = 0.45 atm + 2x E)  equilibrium P<sub>NO2</sub> = 0.45 atm + 1/2 x 2 NO (g) + O₂(g) K p = 4.48*10- 13 A pressure of 0.45 atm of NO₂ is introduced into a container and allowed to come to equilibrium. Complete the ICE equilibrium table shown below to get started. Partial pressure S2NO₂ 2 NO O₂Initial 0.45 M Change At equilibrium -Refer to Exhibit 14-6. Upon constructing an ICE table, what expression would be obtained that represents the equilibrium partial pressure of NO₂ as it reaches equilibrium?


A) equilibrium PNO2 = 0.45 atm - x
B) equilibrium PNO2 = 0.45 atm + x
C) equilibrium PNO2 = 0.45 atm - 2x
D) equilibrium PNO2 = 0.45 atm + 2x
E) equilibrium PNO2 = 0.45 atm + 1/2 x

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What is the molar solubility of Ag2SO4 in 0.11 M Na2SO4? K sp(Ag2SO4) = 1.5×10 - 5


A) [Ag2SO4] = 1.2×10 - 9 M
B) [Ag2SO4] = 3.4×10 - 5 M
C) [Ag2SO4] = 6.8×10 - 5 M
D) [Ag2SO4] = 5.8×10 - 3 M
E) [Ag2SO4] = 8.3×10 - 3 M

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What is the molar solubility of Al(OH) 3, given K sp[Al(OH) 3] = 3×10 - 34?


A) [Al(OH) 3] = 2.2×10 - 12 M
B) [Al(OH) 3] = 1.8×10 - 9 M
C) [Al(OH) 3] = 3.2×10 - 9 M
D) [Al(OH) 3] = 4.2×10 - 9 M
E) [Al(OH) 3] = 9.5×10 - 9 M

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What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!) Na2 O₂(s) + CO₂ (g) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)   Na2 CO3(s) + O₂(g)


A) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)
B) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)
C) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)
D) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)
E) What is the equilibrium constant expression for the following unbalanced equation at equilibrium? (Pay careful attention to the phase indicators!)  Na<sub>2</sub> O₂(s)  + CO₂ (g)    Na<sub>2</sub> CO<sub>3</sub>(s)  + O₂(g)  A)    B)    C)    D)    E)

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One liter of solution is made containing 10 - 4 moles of Mn2+ and 10 - 5 moles of Fe2+. The [OH - ] is adjusted to 1.82×10 - 4 M . Which of the following statements is true, given K sp [Mn(OH) 2] = 4.5×10 - 14 and K sp [Fe(OH) 2] = 2.0×10 - 15?


A) Both Mn and Fe will precipitate as hydroxides.
B) Only Fe2+ will precipitate.
C) Only Mn2+ will precipitate.
D) Neither will precipitate.
E) Need more information to draw a conclusion.

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What is the concentration of Ag+ ions in a saturated solution of Ag2CrO4 in water? K sp = 9.0×10 - 12 for Ag2CrO4.


A) 2.1×10 - 4 M
B) 1.0 M
C) 2.6×10 - 4 M
D) 1.3×10 - 4 M
E) 3.0×10 - 6 M

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