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When a nonvolatile solute is added to a volatile solvent,the solution vapor pressure __________,the boiling point __________,the freezing point __________,and the osmotic pressure across a semipermeable membrane __________.


A) decreases,increases,decreases,decreases
B) increases,increases,decreases,increases
C) increases,decreases,increases,decreases
D) decreases,decreases,increases,decreases
E) decreases,increases,decreases,increases

F) A) and B)
G) D) and E)

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Shaving cream is an example of which colloid type?


A) aerosol
B) foam
C) emulsion
D) sol
E) coagulate

F) All of the above
G) B) and E)

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Calculate the molarity of a solution containing KCl and water whose osmotic pressure at 21.6°C is 125 torr.Assume complete dissociation of the salt.


A) 0.00680 M
B) 5.17 M
C) 0.0464 M
D) 0.00340 M
E) 0.0928 M

F) B) and C)
G) A) and E)

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A solution of water and a nonvolatile,nonionizing compound is placed in a tube with a semipermeable membrane on one side.The tube is placed in a beaker of pure water.What initial net effect will occur?


A) Water will flow from the beaker to the tube.
B) Water will flow from the tube to the beaker.
C) The compound will pass through the membrane into the solution.
D) Nothing will move through the membrane either way.
E) Equilibrium is immediately established.

F) A) and B)
G) C) and E)

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How many of the following help determine whether or not a solution forms? I.the polarities of the solute and solvent II.the densities of the solute and solvent III.the probability of the mixed state (of the solution) IV.the energies needed for the solution formation to occur V.the state of matter of the solute (solid,liquid,gas)


A) 1
B) 2
C) 3
D) 4
E) 5

F) D) and E)
G) A) and D)

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How many milliliters of 15.7 M H2SO4 are needed to prepare 600.0 mL of 0.10 M H2SO4?


A) 0.26 mL
B) 94 mL
C) 3.8 mL
D) 1.9 mL
E) 4.8 mL

F) A) and B)
G) A) and C)

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Calculate both the boiling point and the freezing point if 46.0 g of glycerol,C3H5(OH)3,is dissolved in 500.0 g of H2O.

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freezing point = -1.86°C boiling point =...

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Consider a solution containing liquids A and B where the mole fraction of B is 0.60.Assuming ideality,calculate the mole fraction of A in the vapor at equilibrium with this solution at 25°C.(The vapor pressures of pure liquid A and B at 25°C are 117.7 torr and 400.0 torr,respectively. )


A) 0.16
B) 196
C) 0.31
D) 3.40 ×\times 10-3
E) 4.90 ×\times 10-3

F) A) and D)
G) A) and E)

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A solution containing 292 g of Mg(NO3) 2 per liter has a density of 1.108 g/mL.The molality of the solution is:


A) 2.00 m
B) 2.41 m
C) 1.77 m
D) 6.39 m
E) none of these

F) B) and C)
G) B) and D)

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In a 0.1 molar solution of NaCl in water,which one of the following will be closest to 0.1?


A) The mole fraction of NaCl.
B) The mass fraction of NaCl.
C) The mass percent of NaCl.
D) The molality of NaCl.
E) All of these are about 0.1.

F) A) and B)
G) B) and E)

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Calculate the molarity of a solution of magnesium chloride with a concentration of 26.8 mg/mL.


A) 0.563 M
B) 0.281 M
C) 0.141 M
D) 3.55 M
E) 0.448 M

F) None of the above
G) A) and B)

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Consider a solution containing liquids A and B where the mole fraction of B is 0.60.Assuming ideality,calculate the mole fraction of B in the vapor at equilibrium with this solution at 25°C.(The vapor pressures of pure liquid A and B at 25°C are 129.4 torr and 400.0 torr,respectively. )


A) 0.18
B) 0.22
C) 0.33
D) 0.78
E) 0.82

F) C) and E)
G) A) and D)

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What is the freezing point of an aqueous 1.58 molal NaCl solution? (Kf = 1.86°C/m)


A) -2.94°C
B) 2.94°C
C) -5.88°C
D) 5.88°C
E) 0.00°C

F) D) and E)
G) All of the above

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A solution of two liquids,A and B,shows negative deviation from Raoult's law.This means that:


A) The molecules of A interact strongly with other A-type molecules.
B) The two liquids have a positive heat of solution.
C) Molecules of A interact weakly,if at all,with B molecules.
D) The molecules of A hinder the strong interaction between B molecules.
E) Molecules of A interact more strongly with B than A with A,or B with B.

F) A) and E)
G) A) and D)

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Which of the following solutions would have the highest osmotic pressure?


A) 0.2 M KBr,potassium bromide
B) 0.2 M MgBr2,magnesium bromide
C) 0.3 M CH3COOH,acetic acid
D) 0.3 M C6H12O6,glucose
E) 0.3 M C12H22O11,sucrose

F) B) and D)
G) A) and E)

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A 6.06-gram sample of a compound is dissolved in 250.grams of benzene.The freezing point of this solution is 1.02°C below that of pure benzene.What is the molar mass of this compound? (Note: Kf for benzene = 5.12°C/m. ) Ignore significant figures for this problem.


A) 30.4 g/mol
B) 122 g/mol
C) 243 g/mol
D) 4.83 g/mol
E) 60.8 g/mol

F) C) and E)
G) B) and D)

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A solution contains 1 mole of liquid A and 3 moles of liquid B.This solution has a vapor pressure of 314 torr at 25°C.At 25°C,liquid A has a vapor pressure of 265 torr and liquid B has a vapor pressure of 355 torr.Which of the following is true?


A) This solution exhibits a positive deviation from Raoult's Law.
B) This solution exhibits a negative deviation from Raoult's Law.
C) This solution is ideal.
D) More information is needed to answer this question.
E) None of these (A-D) .

F) A) and C)
G) B) and E)

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Which of the following solutions has the lowest boiling point?


A) 0.15 M NaCl
B) 0.10 M MgBr2
C) 0.15 M Ba(NO3) 2
D) 0.20 M C2H6O2
E) 0.10 M Fe(NO3) 3

F) D) and E)
G) A) and E)

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A chemist is given a white solid that is suspected of being pure cocaine.When 1.22 g of the solid is dissolved in 15.60 g of benzene,the freezing point is lowered by 1.32°C.Calculate the molar mass of the solid.The molal freezing point constant (Kf)for benzene is 5.12°C/m.

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303 g/mol
1.32°C = 5.12°C/m * ...

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The solubility of O2 in water is 0.590 g/L at an oxygen pressure of around 14.5 atm.What is the Henry's law constant for O2 (in units of mol/L·atm) ?


A) 4.07 ×\times 10-2
B) 1.27 ×\times 10-3
C) 7.86 ×\times 102
D) 2.67 ×\times 10-1
E) None of the above are within 5% of the correct answer.

F) A) and B)
G) C) and D)

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